Journals
  Publication Years
  Keywords
Search within results Open Search
Please wait a minute...
For Selected: Toggle Thumbnails
Evaluating the Characters of Songbirds’ Vocalizations during Mobbing Event in Dark Coniferous Forest Using Bio-acoustic Indicators
WANG Jiangyue, TIAN Jia, ZHOU Zhengyang, MA Xiaoyun, LONG Yu, WANG Rongjiang, LI Sheng
Acta Scientiarum Naturalium Universitatis Pekinensis    2024, 60 (1): 118-126.   DOI: 10.13209/j.0479-8023.2023.099
Abstract683)   HTML    PDF(pc) (15525KB)(103)       Save
This study investigated the acoustic variation of songbirds’ vocalization during mobbing event in the sub-alpine forests using playback experiment and automatic acoustic recording (AAR). We played Glaucidium brodiei vocalization and Phylloscopus trochiloides alarm call to induce songbirds’ mobbing behavior and recorded their response vocalizations using automatic acoustic recorders in the Abies-Picea dark coniferous forest in Wanglang National Nature Reserve, Sichuan Province, during the summer of 2021. Altogether 24 experiments were performed on 12 experiment sites, with a total length of 1057 min acoustic recordings, including 12 G. brodiei vocalization experiments, and 12 P. trochiloides alarm call experiments. A total of 28 species of birds belonging to 17 families and 3 orders were observed to participate in mobbing behavior. By analyzing the acoustic indexes of recordings, it was concluded that 1) both G. brodiei vocalization and P. trochiloides alarm call could trigger mobbing event, during which Phylloscopidae and Paridae species were the majority being involved; 2) during playback period, songbirds’ vocalizations are more intense (G. brodiei experiments: SPLavg=−31.02±4.87 dB vs −42.74±4.68 dB, p = 0.001; P. trochiloides experiments: SPLavg = −33.26±4.05 dB vs −46.38±4.54 dB, p = 0.001) and less complicated (G. brodiei experiments: H = 0.76±0.02 vs 0.80±0.03, p = 0.001; P. trochiloides experiments: H = 0.77±0.02 vs 0.82±0.02, = 0.001) than that of pre-playback period; 3) the variability of acoustic indices from pre-playback to during-playback didn’t change significantly between G. brodiei experiments and P. trochiloides experiments. The results provide a new insight into avian behavior studies in the acoustic aspect, and novel behavioral application scenarios for large-scale soundscape monitoring data. 
Related Articles | Metrics | Comments0
Utilization Status and Development Countermeasures of Mangrove Medicinal Resources in the Marine-Terrestrial Interlaced Zone
WANG Lingli, ZHANG Xin, WANG Jiansong, SHEN Xiaoxue, TANG Lili, LI Ruili
Acta Scientiarum Naturalium Universitatis Pekinensis    2023, 59 (4): 704-718.   DOI: 10.13209/j.0479-8023.2023.041
Abstract307)   HTML    PDF(pc) (971KB)(89)       Save
This study summarizes and reviews Chinese medicinal mangroves’ chemical constituent and medicinal effect researches in the past 50 years. Since 2000, the research on medicinal mangroves has increased exponentially, and the most attention is paid to Pongamia pinnata. 27 kinds of medicinal mangroves have been confirmed, and the main medicinal components include terpenoids, flavonoids, steroids, quinones, carbohydrates, phenylpropanoids and alkaloids. Most medicinal mangroves have anti-tumour, antioxidant and anti-inflammatory effects, and some mangrove plants have unique medicinal effects, including anti-depression and anti-Alzheimer's disease. Existing research mainly focuses on the medicinal effects of mangrove plants, but the pharmacological mechanism needs further study. In view of the problems in medical components and the pharmacological effect of mangroves, some suggestions are put forward for their further development and utilization.
Related Articles | Metrics | Comments0
Effects of Carbon-to-Nitrogen Ratio on Nitrogen and Phosphate Removal in A/O-MBR Wastewater Treatment Process
TAO Huchun, TONG Hao, WANG Jian, HUANG Yilong, ZHANG Lijuan, YANG Kai, DING Lingyun, QIAO Xuejiao, DOU Min, XU Nan
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (4): 680-686.   DOI: 10.13209/j.0479-8023.2022.037
Abstract669)   HTML    PDF(pc) (2075KB)(244)       Save
The changing profiles of NH4+-N, total nitrogen (TN) and total phosphate (TP) were investigated in the A/O-MBR process at high and low carbon-to-nitrogen ratios. By elevating the carbon-to-nitrogen ratio, there was an increase in the removal efficiency of TN from 44.1%±8.9% to 78.5%±7.9%, while the removal efficiency remained unchanged for TP. Metabolite analyses revealed that enhanced metabolism of amino acids contributed significantly to efficient nitrogen removal from wastewater and the up-regulation of riboflavin biosynthesis, further improving the water quality.
Related Articles | Metrics | Comments0
Multimodal Emotion Recognition with Auxiliary Sentiment Information
WU Liangqing, LIU Qiyuan, ZHANG Dong, WANG Jiancheng, LI Shoushan, ZHOU Guodong
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (1): 75-81.   DOI: 10.13209/j.0479-8023.2019.105
Abstract1628)   HTML    PDF(pc) (1064KB)(239)       Save
Different from the previous studies with only text, this paper focuses on multimodal data (text and audio) to perform emotion recognition. To simultaneously address the characteristics of multimodal data, we propose a novel joint learning framework, which allows auxiliary task (multimodal sentiment classification) to help the main task (multimodal emotion classification). Specifically, private neural layers are designed for text and audio modalities from the main task to learn the uni-modal independent dynamics. Secondly, with the shared neural layers from auxiliary task, we obtain the uni-modal representations of the auxiliary task and the auxiliary representations of the main task. The uni-modal independent dynamics is combined with the auxiliary representations for each modality to acquire the uni-modal representations of the main task. Finally, in order to capture multimodal interactive dynamics, we fuse the text and audio modalities’ representations for the main and auxiliary tasks separately to obtain the final multimodal emotion and sentiment representations with the self attention mechanism. Empirical results demonstrate the effectiveness of our approach to multimodal emotion classification task as well as the sentiment classification task.
Related Articles | Metrics | Comments0
A Study of Ecological Water Requirement and Efficiency of Water Allocation Based on Oasis Irrigation Area Scale: A Case of Middle Reaches of Heihe River
MENG Jijun, WANG Jiangwei, WANG Ya, ZHOU Zhen, JIANG Song
Acta Scientiarum Naturalium Universitatis Pekinensis    2018, 54 (1): 171-180.   DOI: 10.13209/j.0479-8023.2017.142
Abstract885)   HTML9)    PDF(pc) (1873KB)(278)       Save

Based on many data sources, such as basic geographic information, land use and cover information and statistic data of irrigation areas, the authors picked agricultural irrigation areas in the middle reaches of Heihe river as a study area and analyzed the spatial-temporal distributions of ecological water requirement with Penman-Monteith equation and NDVI data. Considering the real water diversion and consumption per unit grain yield, the efficiency of water allocation was also analyzed. The results show that the annual potential evapotranspiration is between 800 and 1200 mm and the peak occurs between June and August. Average annual potential evapotranspiration is between 614 and 999 mm while maximum of demand appears from April to August. Ecological water requirement reduces from southeast to northwest gradually which is relatively larger along the Heihe river. Ground water plays major role in water diversion while underground water is minor. The yield of water diversion is the largest in 2008 and irrigation areas which have more water diversions flock around the Heihe river. Overall, water resource allocation overthere is fair good. Water supply-demand rate around Heihe river is generally greater than 1 while it is opposite in Shandan and Minle. Nearly 80% of the irrigation areas can be considered as efficient or relative efficient regions. There are four irrigation districts are inefficient and only one is short of water diversion. Therefore, adjustment of water diversion in some certain regions with promotion of water saving technology can enhance the efficiency of water allocation roundly. The results provide feasible reference to improve the efficiency of water allocation in arid area.

Related Articles | Metrics | Comments0
Case Study of Wuhan Dust Pollution in May 2014
WANG Fenjuan, ZHONG Zhangxiong, WU Shuting, ZHANG Wanchun, LI Qijie, HU Shixiang, WANG Jianmin
Acta Scientiarum Naturalium Universitatis Pekinensis    2015, 51 (6): 1132-1140.   DOI: 10.13209/j.0479-8023.2015.106
Abstract1231)      PDF(pc) (2719KB)(822)       Save

The dust event on May 25–26, 2014 in Wuhan Hubei province was studied by integrating multiplex information including mass concentration, metal element contents of atmospheric particle, vertical particle extinction, backward trajectory, surface meteorological parameters and synoptic analysis. The results show that the dust came from the sandstorm occurred in southern Xinjiang Taklamakan desert and Inner Mongolia Badan Jaran desert and Teng Ko Erh desert and then transported to east and south of China with cold air blowing. The PM10 mass concentration decried along the trajectory, with hourly average exceeding 2000 μg/m3, 1000 μg/m3 and 500 μg/m3 in Lanzhou, Yinchuan and Wuhan respectively. During the dust event, coarse particle was dominant, PM10 concentration increasing rapidly, and proportion of PM2.5 to PM10 decreased to about 35%. The concentrations of dust trace element Ca, V, Ba and Fe increased by about 4 times, percentages of the total element concentration doubled and the concentrations of As, Se, Cr, Cu, Zn and Pb from local anthropogenic sources were 1/5–2/5 of previous levels, percentages of the total element concentration decreasing significantly. Two evident dust deposition processes were recorded by Lidar, and the maximum area of extinction appeared near surface around 500 m with the max value at 0.086 km-1. This paper pilots the analysis method of transporting air pollution using combination of meteorological and environmental measurements.

Related Articles | Metrics | Comments0
Analysis on the Knowledge Structure and Evolution Path of Core Authors in Domestic Cloud Computing Research Areas
WANG Jiandong,LIU Yang,WANG Jimin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract562)      PDF(pc) (626KB)(403)       Save
Based on visual analysis method, the authors analyzed the emergence background and history of cloud computing research. Firstly, the core authors group of cloud computing research area was determined, and a co-word network was constructed using published literature bibliographic data of these authors in the last ten years. Then the community structure sampling algorithm and G-N clustering algorithm were introduced to analyze the overall distribution of the research field. Through counting the membership degree of a keyword to specific research groups, the authors made a comparative analysis on core groups’ research features. Finally, the migration path of core group’s research interest after and before entering this field was analyzed, and the domestic development of cloud computing was divided into several basic stages.
Related Articles | Metrics | Comments0
Learning to Rank Concept Annotation for Text
TU Xinhui,HE Tingting,LI Fang,WANG Jianwen
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract717)      PDF(pc) (1361KB)(440)       Save
This paper proposed an automatic text annotation method (CRM, concept ranking model) based on learning to ranking model. Firstly the authors built a training set of concept annotation manualy, and then used the Ranking SVM algorithm to generate concept ranking model, finally the concept ranking model was used to generate concept annotation for any texts. Experiments show that proposed method has a significant improvement in various indicators compared to traditional annotation methods, and concept annotation results is closer to human annotation.
Related Articles | Metrics | Comments0
Pitch Perception of Harmonic Complex Tones Based on Temporal Model
WANG Jian,GUAN Tian,YE Datian
Acta Scientiarum Naturalium Universitatis Pekinensis   
Orthogonal Design of Xilinhaote Lignite Oxidation with Hydrogen Peroxide in Aqueous Alkali with Microwave-Assisted
LANG Yuqi,FENG Bo,QIN Chunmei,WANG Jian,QI Lu
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract678)      PDF(pc) (430KB)(213)       Save
Microwave-assisted Xilinhaote lignite oxidation with hydrogen peroxide in aqueous alkali were studied by using orthogonal test. Taking the yield of succinic acid as index, the reaction time, reaction temperature, the concentration of H2O2 and the alkali/coal mass ratio were investigated. The highest yield of succinic acid under the optimum reaction conditions was 20.4% (daf). The optimum conditions include reaction temperature 180°C, reaction time 1 hour, alkali/coal mass ratio 1.5:1 and the concentration of H2O2 0.026 mol/L.
Related Articles | Metrics | Comments0
Study on Journal Database Retrieve Behavior of University Users Based on Log Mining
WANG Jiandong,WANG Jimin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract580)      PDF(pc) (459KB)(452)       Save
Based on a large Chinese journals database query log, this paper analyzed the basic features of academic database using behavior, including user access time distribution, special retrieval using proportion, as well as key words length distribution. Furthermore, the search strategy of different universities users was also analyzed. It is found that, according to users from different types of universities (science and engineering, normal, agriculture and forestry, medicine), there is a corresponding difference in search strategy; but as to users from universities of different educational levels (985 project, 211 project, etc), the differences in search strategies do not exist. Finally, by judging the IP address, the paper extracted users’ gender, profession, education level and other demographic variables. The authors analyzed the influence of these variables on their search behaviors, and proposed a factor model of university users’ search strategies.
Related Articles | Metrics | Comments0
Studies on Power Li-Ion Secondary Battery System for EV and HEV
AN Fuqiang,Qilu,WANG Jian,ZHANG Ding,CHEN Hui,MAO Yongzhi,LIU Zhengyao
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract769)            Save
Electrochemical performances of Mn-series power batteries produced by MGL were studied, and compared with LiFePO4 power batteries of other companies. The results indicate that the high capacity and high power batteries with spinel LiMn2O4 and multi metal oxides as cathode materials not only have high voltage, high energy density, good high and low temperature properties, excellent rate of charge and discharge, stable thermal performance, but also show the linear of state of charge-open-circuit voltage (SOC-OCV) relationship, and then the battery manage system (BMS) can be easily controlled. Therefore, Mn-series power batteries will be the important direction for future power batteries.
Related Articles | Metrics | Comments0
Application of Network Generalized Extreme Value Model to Estimate Residential Location and Commute Mode Choice
LI Xia,SHAO Chunfu,QU Tianshu,YANG Liya,WANG Jiangfeng
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract715)            Save
Relationship between jobs-housing spatial distribution and travel to work were studied from a microscopic perspective. Based on random utility maximization theory, factors depicting the individual and socio-economic characteristics and attribute of travel and land use are defined as exogenous variables, meanwhile, the model choice sets are the combination of residential location choice and commute mode choice subsets. Discrete choice model specified as Network Generalised Extreme Value(NetworkGEV) is employed to investigate the joint decisions of where to live and how to get to workplace which attempts to describe the change of aggravated traffic congestion and discover the potential change caused by residential relocation and travel mode shift under different employment location patterns. This model is estimated in Biogeme, and the direct and cross elasticities are calculated to analyze the change of alternatives probability brought by factors variation. The results reveal that the model yields plausible estimation of exogenous variables in the joint residential location and travel mode choice context. Compared with suburban commuters, commuters in CBD are more sensitive to the increase of travel time and intend to change travel mode and residential location thus trading off the disutility of traffic congestion.
Related Articles | Metrics | Comments0
Synthesis and Electrochemical Performance Study of Cathode Material Li(CoxNiyMn1-x-y)O2 for High Power Lithium Ion Secondary Battery
Qilu,JIANG Weijun,WANG Jian,MAO Yongzhi,CHEN Hui,WU Ningning,LEI Xiangli
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract701)            Save
High capacity and high voltage composite metal oxide Li(CoxNiyMn1-x-y)O2 used in high power lithiumion secondary batteries was synthesized by chemical method. 8 Ah high power lithium ion batteries with this cathode material were fabricated and studied, and the battery system were tested in Hybrid Electric Vehicle (HEV). The results show that the battery system holds excellent cycle performance and uniformity. Furthermore, the highest temperature increase of individual batteries is just 5℃ which means the battery system holds good thermal stability. Consequently this battery system fits HEV very well.
Related Articles | Metrics | Comments0
The Demand Study of the Technological Equipments for Disposal to the Emergency Rescue of a Great Earthquake in China
HU Weijian,SHANG Hong,SI Hongbo,NING Baokun,QU Guosheng,WANG Jianping,LI Lei,ZHANG Tiangang,SUN Gang,ZHAO Lanying,LI Li,XIE Peng,ZHANG Haitao,LIU Kang,DING Lu,GAO Yang,XU Yifan,LIU Jingjing,LIU Xuan
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract775)            Save
Through analyse of characters of China's earthquake and comparison of present technology conditions of the emergency rescue equipments in the domestic and international vital catastrophes. Based on “the project of the scientific research concerning Wenchuan 8.0 Earthquake Emergency Rescue”in China, the authors study sufficiently the various impediments factors to implement the earthquake catastrophe rescue on the aspects of technique and equipment in china. Furthermore, there are the following many considerations, for example, the communication command and management of the emergency rescue, the collection and transmission of the information from the rescue locale, the rescue and accessorial systems of the experts decision-making, especially, after the vital earthquake, the actions of searching lifes in the ruins, the rescue and safe protection suitable to the complex conditions of the landslides and the blocked traffic, the environment of the tumbled large building constructs and the small spaces in the ruins and so on. The basic technological equipment demands are presented to guarantee the effective rescue when a great earthquake occurs in China anywhere.
Related Articles | Metrics | Comments0
Application of Three-Dimension Geological Modeling and Visualization Systemin Anqing Copper Mineral Exploration
CONG Weiqing,PAN Mao,LV Caiyu ,WANG Jianqing,LI Changqing
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract548)            Save
The overall structure and principal functions of three-dimension geological modeling and visualization system were discussed. It was used in Anqing copper mineral exploration. The system is mainly composed of three-dimension structure modeling , three-dimensional attribute modeling and three-dimensional geological visualization. Based on the modeling functions and the actual data of Anqing copper mineral exploration, three-dimensional geological models were built. Through the visual analysis, good prospects for exploration were revealed by the extension trend to east southerly direction of copper iron ore. It shows that the three-dimensional geological modeling and visualization system will be very helpful for enhancing the efficiency and accuracy of mineral prospecting to build.
Related Articles | Metrics | Comments0
A Dual Finite Fields Algorithm for Elliptic Curve Cryptosystem and FPGA Implementation
WANG Jian,JIANG Anping,SHENG Shimin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract651)            Save
A dual finite fields algorithm for elliptic curve cryptosystem(ECC)is presented. It can be used in two kinds of finite fields, which are Galois fields GF(p) and GF(2m) for arbitrary prime numbers and irreducible polynomials respectively. An arithmetic unit, which can perform all dual Galois fields' arithmetic operations, including addition, subtraction, multiplication, squaring, inversion and division, is designed for the ECC. Furthermore, the authors describes a FPGA implementation of ECC. It can efficiently handle requests for different ECC key length and different curves in GF(p) and GF(2m).
Related Articles | Metrics | Comments0
Study of Evapotranspiration Processes Simulationin Arid and Semi, Arid Regions
LIU Shuhua,YU Fei,LIU Heping,ZHANG Chenyi,LIANG Fuming,WANG Jianhua
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract681)            Save
An integrated and flexible numerical model has been established to simulate and study the evaporation, transpiration and evapotranspiration mechanism of moisture on land, surface with complex vegetative cover. To better simulate this process, the authors apply some reasonable modifications to the parameterization of edaphic process too. The model is used to simulate the process of Zhangye station during IOP2 of HEIFE, and the results are generally in good agreement with observations. It indicates that the model developed can be used to study the interaction between land surface and atmospheric boundary layer over arid and semi, arid regions. Thus it can be used on evaluating the environment and shaping measures for sustainable development.
Related Articles | Metrics | Comments0
A Dual Field Modular Inversion Algorithm and Hardware Implementation
WANG Jian,JIANG Anping,SHENG Shimin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract661)            Save
The finite field arithmetic is the base of cryptography and modular inversion is the kernel arithmetic operation. The authors present a dual field modular inversion algorithm. The 256-bit inversion circuit based on the proposed algorithm can be used at the 167MHz clock frequency. It also has an improvement in area complexity compared with other designs.
Related Articles | Metrics | Comments0
High Power Li-ion Secondary Batteries Based on New Cathode Materials
WANG Jian1), LI Linxiang1), Qilu2, 3), AN Ping1)
(1)CITIC Guoan Mengguli New Energy Technology Co., Ltd., Beijing,102200; 2) New Energy Materials and Technology Laboratory, Department
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract718)            Save
The 18650 lithium-ion secondary battery is prepared with spinel LiMn2O4 cathode material, and major factors affecting lithium-ion secondary battery's discharge performance under big currents are analyzed, including tab, electrode and electrolyte. Another 18650 high power lithium-ion secondary battery is prepared with innovative cathode material LiMnxNiyCozO2, which presents superior performance. The battery endures continuous discharge under 10C and quick charge under 8C and presents excellent cycling and storage performance. The development of 18650 high power lithium-ion secondary battery provides the experimental references for high power lithium-ion secondary battery for hybrid electric vehicle (HEV).
Related Articles | Metrics | Comments0
Numerical Simulation of Features of Surface Boundary-Layer over Beijing Area
HU Xiaoming,LIU Shuhua,LIANG Fuming,WANG Jianhua,LIU Heping,LI Ju,WANG Yingchun
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract653)            Save
The non-hydrostatic mesoscale model MM5.V3 is used to simulate the wind field, temperature field etc. of the atmospheric boundary layer over Beijing Area with the mesh resolution of 1km. The simulation results show that the numerical model can successfully simulate the heat island effect and the wind field and temperature field, which are affected by the complicated topography and urban heat island. The results show that: (1) The surface temperature in the central Beijing is 6--8℃ higher than that in the suburbs. (2) Due to the unique topography the wind of Beijing area during the day time is southern anabatic wind and is northern katabatic wind in the night.
Related Articles | Metrics | Comments0
Observational Study of Wind Fields, Temperature Fields over Beijing Area in Summer and Winter
HU Xiaoming,LIU Shuhua,LIANG Fuming,WANG Jianhua,LIU Heping,WANG Yingchun,LI Ju
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract712)            Save
The wind fields and temperature fields data provided by "D files" from 14 surface observation stations around Beijing area are used to produce the mean wind fields and the mean temperature fields over Beijing area in summer and winter. Such results are gotten: (1) Due to the unique topography the wind of Beijing area during the day time is southern anabatic wind and in the night is northern katabatic wind in summer. In winter, this phenomenon disappears due to the affect of the strong synoptic systems. (2) In summer, Haidian and Fengtai lie in an area with high temperature. These areas are the main are as of the Urban Heat Island over Beijing area. In winter Haidian and the area north to Haidian are high temperature areas during the night.
Related Articles | Metrics | Comments0
The 3rd Generation Search Engine and WebGather Version 2.0
LEI Ming,WANG Jianyong,ZHAO Jianghua,SHAN Songwei,CHEN Baojue
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract253)            Save
With the rapid growing of WWW, significant progress has been made in search engine research area. The evolvement of search engine and the system architecture for the 3rd generation are reviewed. More emphasis will be given on some core technologies related to search engines of the 3rd generation. For example, the massive and efficient web-crawling technology, the method of hyper-link analysis, and the user behavior analyzing technology will be described in detail. In addition, it is also presented the recent research progress of WebGather, which is a typical search engine of 3rd generation. Several research hotspots for future search engine systems are pointed out in the conclusion.
Related Articles | Metrics | Comments0
The 3rd Generation Search Engine and WebGather Version 2.0
LEI Ming,WANG Jianyong,ZHAO Jianghua,SHAN Songwei,CHEN Baojue
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract774)            Save
With the rapid growing of WWW, significant progress has been made in search engine research area. The evolvement of search engine and the system architecture for the 3rd generation are reviewed. More emphasis will be given on some core technologies related to search engines of the 3rd generation. For example, the massive and efficient web-crawling technology, the method of hyper-link analysis, and the user behavior analyzing technology will be described in detail. In addition, it is also presented the recent research progress of WebGather, which is a typical search engine of 3rd generation. Several research hotspots for future search engine systems are pointed out in the conclusion.
Related Articles | Metrics | Comments0
The Reaction Mechanism and Synthetic Application of α-Diazo Carbonyl Compounds
JIANG Nan,WANG Lin,WANG Jianbo
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract295)            Save
α-Diazo carbonyl compounds can be decomposed under various conditions and result in diverse types of chemical transformations. For this reason, their application in organic synthesis have attracted considerable attention. In order to gain deep insight into the mechanism of the synthetically well established Rh(Ⅱ) mediated intramolecular C-H insertion reaction, the classic physical organic chemistry method, the Hammett linear free energy correlation, has been applied. In the development of new synthetic methodologies of α-diazo carbonyl compounds, it was found that Cu(acac)2 can effectively promote the diazo decomposition and resulted in selective intramolecular N-H insertion. On the other hand, the Wolff rearrangement of the α-diazo carbonyl compounds catalyzed by Ag(Ⅰ) has been applied to the efficient synthesis of optically pure γ-lactams.
Related Articles | Metrics | Comments0
The Reaction Mechanism and Synthetic Application of α-Diazo Carbonyl Compounds
JIANG Nan,WANG Lin,WANG Jianbo
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract751)            Save
α-Diazo carbonyl compounds can be decomposed under various conditions and result in diverse types of chemical transformations. For this reason, their application in organic synthesis have attracted considerable attention. In order to gain deep insight into the mechanism of the synthetically well established Rh(Ⅱ) mediated intramolecular C-H insertion reaction,the classic physical organic chemistry method, the Hammett linear free energy correlation, has been applied. In the development of new synthetic methodologies of α-diazo carbonyl compounds, it was found that Cu(acac)2 can effectively promote the diazo decomposition and resulted in selective intramolecular N-H insertion. On the other hand, the Wolff rearrangement of the α-diazo carbonyl compounds catalyzed by Ag(Ⅰ) has been applied to the efficient synthesis of optically pure γ-lactams.
Related Articles | Metrics | Comments0
Time Characteristics of Tectonic Evolution
WANG Jianjun,QIAN Xianglin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract776)            Save
The implication of tectonic cycle in terms of plate tectonics theory is totally different from the one in early knowledge, which laid stress on uncomformity. The picture of tectonics evolution that emerges from the orogeny history study of the Phanerozoic Tethyside system and Precambrian block in Asia is one of a harmony. The continent crust demonstrated an original character of plate tectonics in the earth's early stage. The co-orogeny and post-orogeny deforming show a continuous character. Large-scale strike-slip faults play significant roles in course of tectonic evolution, since they regulate the gradual tectonic progress, and which is identified obviously in Northwest China and Tethyside system. Examining the matter from the view of global tectonics, the concept of orogenic episode is unavailable. The orogeny event, such as Caledonian, Hercynian, and Alpine cycle can't be viewed as a dependent phase in geological succession, since the latter is a continuous one.
Related Articles | Metrics | Comments0